弹塑性变形与杂散电流耦合作用下低碳钢腐蚀劣化行为分析理论模型

A Theoretical Model for Corrosion Degradation of Mild Steel under Coupled Elastoplastic Deformation and Stray Current

杂散电流与载荷共同作用下, 金属材料的腐蚀劣化行为是影响其耐久性的关键。本文面向工程常用低碳钢, 建立了弹塑性变形与杂散电流耦合作用下低碳钢腐蚀行为发展演化预测理论模型和数值计算方法, 系统研究了杂散电流频率 (1~100Hz) 及应变水平 (弹性变形0. 1%和0. 2%、塑性变形1. 0%和2. 0%) 对固液界面电流响应与腐蚀动力学过程的影响。研究结果表明: 低频杂散电流作用下腐蚀电化学反应占主导, 而高频下双电层充放电过程逐渐主导界面响应; 弹性变形仅轻微促进腐蚀, 而塑性变形因引入大量缺陷显著加速腐蚀, 峰值腐蚀电流密度在塑性阶段增幅可达15. 76%~19. 99%。所开展的工作为极端条件下金属材料与结构的腐蚀疲劳评定、预测与防护提供了科学依据。

The corrosion degradation behavior. of metallic materials under the combined action of stray current and mechanical load is crucial for their durability. This study targets mild steel, a material commonly used in engineering. A theoretical model and corresponding numerical method are established to predict the evolution of corrosion behavior. in mild steel under the coupled action of elastoplastic deformation and stray current. The effects of stray current frequency (1-100Hz) and strain level (elastic strains of 0. 1% and 0. 2%, plastic strains of 1. 0% and 2. 0%) on the current response at the solid-liquid interface and the corrosion kinetics are systematically investigated. The results indicate that corrosion electrochemical reactions dominate under low-frequency stray current, whereas the charging/discharging process of the electric double layer progressively governs the interfacial response at high frequencies. Elastic deformation only slightly promotes corrosion, whereas plastic deformation significantly accelerates it due to the introduction of numerous defects. The peak corrosion current density increases by 15. 76% to 19. 99% during the plastic stage. This work provides a scientific basis for assessing, predicting, and protecting against corrosion fatigue of metallic materials and structures under extreme conditions.