石墨烯改性超高性能混凝土综述

李子豪; LI Zihao; 于峰; YU Feng; 李洪艳; LI Hongyan; 王欣悦; WANG Xinyue; 韩宝国; HAN Baoguo

doi:10.48014/ems.20250317001

石墨烯改性超高性能混凝土综述

A Review of Graphene-Modified Ultra-High-Performance Concrete

工程材料与结构 2025年第4卷第2期页码[5-29] 下载全文[9.9MB]

摘要

石墨烯作为二维纳米碳材料, 既具有优异的力学性能, 又具有优异的电导率和热导率, 同时密度低、热稳定性和化学稳定性好, 将其与超高性能混凝土 (Ultra-high performance concrete, 简称UHPC) 复合, 有望发展兼具优异力学性能、耐久性能和多功能/智能性能的结构-功能一体化UHPC。本文系统梳理了石墨烯改性超高性能混凝土的研究进展, 首先探讨了不同种类石墨烯材料特性及其分散技术, 然后分析了石墨烯改性超高性能混凝土的早期理化性能 (如水化性能、流变性能、工作性能) 以及凝结硬化后的性能 (如静态/动态力学性能、耐久性及多功能/智能特性) , 最后总结讨论了石墨烯改性UHPC后续发展面临的挑战和发展策略。该综述有助于推动石墨烯改性UHPC的研究, 并为混凝土材料的可持续发展提供指导。

Abstract

Graphene, as a two-dimensional nanocarbon material, exhibits excellent mechanical properties, along with outstanding electrical and thermal conductivity, low density, and superior chemical and thermal stability. Its incorporation into ultra-high performance concrete (UHPC) offers significant potential for developing structurally and functionally integrated UHPC with enhanced mechanical strength, durability, and multifunctional or smart capabilities. This review systematically summarizes recent advances in graphenemodified UHPC research. It begins with an overview of different types of graphene materials and their dispersion techniques, followed by a detailed analysis of their effects on the early-stage physicochemical properties of UHPC (e. g. , hydration behavior, rheological properties, and workability) and its hardened-state performance (e. g. , static and dynamic mechanical properties, durability, and multifunctional/smart functionalities) . Finally, the current challenges and strategic directions for further development of graphenemodified UHPC are critically discussed. This comprehensive review aims to accelerate research progress in graphene-modified UHPC and provide valuable insights for sustainable development of ultra-high-performance concrete materials.

DOI

10.48014/ems.20250317001

文章类型

综述

收稿日期

2025-03-17

接收日期

2025-03-25

出版日期

2025-06-28

关键词

石墨烯, 超高性能混凝土, 分散, 流变性能, 力学性能, 多功能/智能

Keywords

Graphene, ultra-high-performance concrete, dispersion, rheological properties, mechanical properties, multifunctional and smart properties

作者

李子豪¹, 于峰², 李洪艳³, 王欣悦^4,*, 韩宝国^5,*

Author

LI Zihao¹, YU Feng², LI Hongyan³, WANG Xinyue^4,*, HAN Baoguo^5,*

所在单位

1. 大连理工大学土木工程学院, 大连 116024
2. 大连理工大学土木工程学院, 大连 116024
3. 东南大学材料科学与工程学院, 南京 211189
4. 天津大学建筑工程学院, 天津 300072
5. 大连理工大学土木工程学院, 大连 116024

Company

1. School of Civil Engineering, Dalian University of Technology, Dalian 116024, China
2. School of Civil Engineering, Dalian University of Technology, Dalian 116024, China
3. School of Materials Science and Engineering, Southeast University, Nanjing 211189, China
4. School of Civil Engineering, Tianjin University, Tianjin 300072, China
5. School of Civil Engineering, Dalian University of Technology, Dalian 116024, China

浏览量

下载量

基金项目

本项研究得到了国家自然科学基金项目(资助号:52308236,52368031,52178188)、全国建材行业重大科技攻关“揭榜挂帅”项目(资助号:2023JBGS10-02)、辽宁省自然联合基金(资助号:2023-BSBA-077)和中央高校基本科研业务费(资助号:DUT24GJ202)的资助。

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引用本文

李子豪, 于峰, 李洪艳, 等. 石墨烯改性超高性能混凝土综述[J]. 工程材料与结构, 2025, 4(2): 5-29.

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LI Zihao, YU Feng, LI Hongyan, et al. A review of graphene-modified ultra-high-performance concrete[J]. Engineering Materials and Structures 2025, 4(2): 5-29.