多孔生物质衍生炭材料制备及储钠性能研究

韩嘉帅; HAN Jiashuai; 刘冬明; LIU Dongming; 杨恩恩; YANG Enen; 刘思洋; LIU Siyang; 金鑫; JIN Xin; 胡方圆; HU Fangyuan

doi:10.48014/pcms.20220603001

多孔生物质衍生炭材料制备及储钠性能研究

Preparation of Porous Biomass-Derived Carbon Material and Its Sodium Storage Capacity

中国材料科学进展 2022年第1卷第1期页码[25-37] 下载全文[7.4MB] [HTML]

摘要

采用来自中国新疆地区的生物质———恰玛古为碳前驱体, 充分利用其体内固有的孔道结构, 并在此基础上进行预碳化和活化, 设计制备了多孔生物质衍生炭材料 (BDPC) 。利用扫描电子显微镜、X射线衍射、Raman光谱、X射线光电子能谱和氮气吸/脱附测试对材料进行结构与物相分析；通过循环伏安法、恒流充放电、循环、倍率和电化学阻抗测试表征了该材料应用于储钠阳极的电化学性能。结果表明, BDPC-600因含有氮、氧杂原子 (含量分别为3. 36at. %和7. 61at. %) , 故具有良好的储钠性能：当电流密度为0. 1A/g时, 经过100次循环充放电过程后, 可逆容量为187. 7mAh/g, 容量保持率为88. 7%。此外, BDPC-900由于具有较大的比表面积 (2396. 60m2/g) 和孔容 (1. 70cm3/g) , 故具有优异的倍率性能。

Abstract

Biomass-derived porous carbon (BDPC) was designed and prepared from Qamgur, a biomass from Xinjiang, China, as the carbon precursor, by pre-carbonization and activation, while retaining Qamgur’s inherent pore structure. The microstructure, phase composition and pore structure of the material were analyzed by scanning electron microscope (SEM) , X-ray diffraction (XRD) , Raman spectroscopy, X-ray photoelectron spectroscopy (XPS) and nitrogen adsorption desorption test; The electrochemical properties of the material as a sodium storage anode were characterized by cyclic voltammetry, constant current charge-discharge, cycling, magnification and electrochemical impedance measurements. The results show that BDPC- 600 has good sodium storage performance because it contains nitrogen and oxygen heteroatoms (the contents are 3. 36 at. % and 7. 61 at. %, respectively) . At 0. 1A/g current density, after 100 cycles of charge and discharge, the reversible capacity is 187. 7mAh/g, and the capacity retention rate is 88. 7%. In addition, BDPC-900 has excellent magnification performance due to its large specific surface area (2396. 60 m2/g) and pore volume (1. 70cm3/g) .

DOI	10.48014/pcms.20220603001
文章类型	研究性论文
收稿日期	2022-06-03
接收日期	2022-06-25
出版日期	2022-06-28
关键词	生物质炭材料, 阳极, 储钠, 放电比容量
Keywords	Biomass carbon material, anode, sodium storage, specific discharge capacity
作者	韩嘉帅, 刘冬明, 杨恩恩, 刘思洋, 金鑫, 胡方圆^*
Author	HAN Jiashuai, LIU Dongming, YANG Enen, LIU Siyang, JIN Xin, HU Fangyuan^*
所在单位	大连理工大学材料科学与工程学院, 大连 116024
Company	School of Materials Science and Engineering, Dalian University of Technology, Dalian 116024, China
浏览量	910
下载量	565
基金项目	中国石油科技创新基金项目(2021DQ02-1001)、兴辽英才青年拔尖项目(XLYC1907144)、大连理工大学“星海优青” 项目(X20200303)资助
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引用本文	韩嘉帅, 刘冬明, 杨恩恩, 等. 多孔生物质衍生炭材料制备及储钠性能研究[J]. 中国材料科学进展, 2022, 1(1): 25-37.
Citation	HAN Jiashuai, LIU Dongming, YANG Enen, et al. Preparation of porous biomass-derived carbon material and its sodium storage capacity[J]. Progress in Chinese Materials Sciences, 2022, 1(1): 25-37.