纳米工程化超高性能水泥基复合材料综述

王丹娜; WANG Danna; 努尔艾力·麦麦提图尔荪; NUERAILI Maimaitituersun; 王欣悦; WANG Xinyue; 韩宝国; HAN Baoguo

doi:10.48014/ems.20241230001

纳米工程化超高性能水泥基复合材料综述

A Review on Nano-Engineered Ultra-High Performance Cementitious Composites

工程材料与结构 2024年第3卷第4期页码[46-66] 下载全文[7.9MB] [HTML]

摘要

超高性能水泥基复合材料 (Ultra-high performance cementitious composites, 简称UHPCC) 是近30年来最具创新和潜力的新一代水泥基复合材料。然而, 低孔隙和高密实度赋予UHPCC极高强度的同时, 也带来了材料毛细孔负压大、自收缩现象严重、水化速率快、温度应力大等问题。具有小尺寸效应和纳米效应的纳米填料有助于改善多尺度的水泥基原材料在纳米尺度上的连续性, 弥补水泥基复合材料的纳米结构缺陷, 从而自下而上地改性其力学、耐久等性能, 同时赋予水泥基复合材料功能特性。其中, 碳纳米管 (Carbon nanotubes, 简称CNTs) 既拥有碳纤维材料的固有特性, 又具有高导电导热、耐热耐蚀等特性, 是一种性能优异的纳米填料以及复合材料改性填料。基于此, 本文总结了UHPCC以及纳米填料, 尤其是CNTs复合水泥基材料的相关性能与研究现状, 分析了UHPCC超高性能的优化方法。纳米改性UHPCC有望从根本上设计水泥基复合材料的结构与性能, 在性能上取长补短、产生协同效应, 是研发UHPCC的创新性途径之一。

Abstract

Ultra-high performance cementitious composites (UHPCC) are the most innovative and promising new generation of cementitious composites over the past three decades. However, while low porosity and high density contribute to the extremely high strength of UHPCC, they also lead to issues such as high capillary suction, severe autogenous shrinkage, rapid hydration rate, and large temperature stresses within the material. Nanofillers with small size and nano effects are helpful to improve the continuity of cementitious raw materials at the nanoscale across multiple scales. They make up for the nanostructure defects of cementitious composites, thereby modifying their mechanical and durability properties from the bottom up, and at the same time endowing cement-based composite materials with functional properties. Carbon nanotubes ( CNTs) not only have the inherent characteristics of carbon fiber materials, but also have high electrical conductivity, thermal conductivity, heat resistance, and corrosion resistance, which is an excellent type of nanofillers and an ideal reinforcing filler for composites. Based on this, this paper summarizes the relevant properties and research status of UHPCC, nanofillers reinforced cementitious composites, particularly CNTs reinforced cementitious composites, and analyzes the optimization methods for achieving the ultrahigh performance of UHPCC. Nano-modification of UHPCC holds promise for fundamentally designing the structure and properties of cementitious composites, achieving complementary strengths and synergistic effects in performance. It is one of the innovative approaches in the development of UHPCC.

DOI	10.48014/ems.20241230001
文章类型	综述
收稿日期	2024-12-01
接收日期	2024-12-12
出版日期	2024-12-28
关键词	超高性能水泥基复合材料, 纳米改性, 碳纳米管, 性能, 机理
Keywords	Ultra-high performance cementitious composites, nano-modification, carbon nanotubes, performances, mechanisms
作者	王丹娜¹, 努尔艾力·麦麦提图尔荪², 王欣悦³, 韩宝国^4,*
Author	WANG Danna¹, NUERAILI Maimaitituersun², WANG Xinyue³, HAN Baoguo^4,*
所在单位	1. 浙江水利水电学院建筑工程学院, 杭州 310018 2. 喀什大学交通学院, 喀什 844000 3. 天津大学建筑工程学院, 天津 300072 4. 大连理工大学建设工程学院, 大连 116024
Company	1. School of Civil Engineering and Architecture, Zhejiang University of Water Resources and Electric Power, Hangzhou 310018, China 2. School of Transportation, Kashi University, Kashi 844000, China 3. School of Civil Engineering, Tianjin University, Tianjin 300072, China 4. School of Civil Engineering, Dalian University of Technology, Dalian 116024, China
浏览量	559
下载量	212
基金项目	本项研究得到了国家自然科学基金(资助号:52178188,52308236,52368031),全国建材行业重大科技攻关“揭榜挂帅”项目(资助号:2023JBGS10-02),辽宁省自然联合基金(资助号:2023-BSBA-077)和中央高校基本科研业务费(资助号:DUT24GJ202)的资助。
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引用本文	王丹娜, 努尔艾力·麦麦提图尔荪, 王欣悦, 等. 纳米工程化超高性能水泥基复合材料综述[J]. 工程材料与结构, 2024, 3(4): 46-66.
Citation	WANG Danna, NUERAILI Maimaitituersun, WANG Xinyue, et al. A review on nano-engineered ultra-high performance cementitious composites[J]. Engineering Materials and Structures 2024, 3(4): 46-66.